Download PDF by Gabrielle J Persley, L R MacIntyre: Agricultural biotechnology : country case studies : a decade

By Gabrielle J Persley, L R MacIntyre

ISBN-10: 0851997066

ISBN-13: 9780851997063

Following on from past titles during this sequence, this quantity provides additional fabric generated through the area Bank/ISNAR/Australian govt biotechnology examine. It covers the current prestige and destiny clients for the appliance of biotechnology to resolve agricultural and environmental difficulties in a couple of constructing international locations. specific concentration is given directly to advancements that experience taken position over the past decade.

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By Gabrielle J Persley, L R MacIntyre

ISBN-10: 0851997066

ISBN-13: 9780851997063

Following on from past titles during this sequence, this quantity provides additional fabric generated through the area Bank/ISNAR/Australian govt biotechnology examine. It covers the current prestige and destiny clients for the appliance of biotechnology to resolve agricultural and environmental difficulties in a couple of constructing international locations. specific concentration is given directly to advancements that experience taken position over the past decade.

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V w ( R ) i s t h e van der Waals volume o f s u b s t i t u e n t R c a l c u l a t e d by B o n d i ' s method ( 5 ) . R i s d e d i c a t e d t o t h e more b u l k y g r o u p i n comparison w i t h R group. V w ( R ) i s t h e van der Waals volume o f R group i n e x c e s s o f t h a t of a m e t h y l g r o u p . I n o t h e r words, i n t h e case o f a h y d r o g e n o r a m e t h y l group as R , V w ( R ) was e s t i m a t e d as 0. A l o g P i s t h e summation of t h e 1o c t a n o l / w a t e r p a r t i t i o n c o e f f i c i e n t s c a l c u l a t e d by C i p p e n ' s method {6) f o r p y r i d i n e r i n g and t h e o t h e r h e t e r o c y c l i c m o i e t y e x c e p t t h e s u l f o n y l u r e a b r i d g e .

ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 51 52 SYNTHESIS AND CHEMISTRY OF AGROCHEMICALS III 2 S i n c e the c o e f f i c i e n t s f o r Vw(R') and V w ( R ) a r e n e g a t i v e , t h e l a r g e r R and R d e c r e a s e t h e h e r b i c i d a l a c t i v i t y . The optimum v a l u e f o r A l o g P w i l l e x i s t b e c a u s e t h e e q u a t i o n i s q u a d r a t i c f o r i t . 892. T h i s v a l u e i s l a r g e r than t h e A l o g P f o r SL-950 ( 1 .

A c O H , g) N H / C H C 1 , h) MeOH, 2 3 2 3 NEt3/EDC, i ) t - B u N H / C H C l , 2 2 2 1 2 2 2 k) C F C 0 H , 1) I . H SO* 3 2 2 j ) Me AlN(R )R /benzene-CH Cl , 2 f 2 2 m) BnOH,K C0 /DMSO, n) c . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1992. Synthesis and QSAR of Pyridylsulfonylurea Herbicides MURAI ET AL. W. C. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 2 47 48 SYNTHESIS AND CHEMISTRY OF AGROCHEMICALS III p r e p a r e d from 2 , 6 - d i c h l o r o - 3 - t r i f l u o r o m e t h y l p y r i d i n e by t h e s i d e - c h a i n t r a n s h a l o g e n a t i o n , were t r e a t e d w i t h b e n z y l a l c o h o l to i n t r o d u c e b e n z y l o x y p r o t e c t i n g group a t t h e 6 - p o s i t i o n by a nucleophilic substitution.

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Agricultural biotechnology : country case studies : a decade of development by Gabrielle J Persley, L R MacIntyre


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